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Chemist? Pls Explain New Octane Boost

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Old Nov 13, 2008 | 08:54 AM
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Default Chemist? Pls Explain New Octane Boost

Haven't seen a thread with this particular octane issue, so...

Gas here has had the pump stickers "may contain ethanol" for quite awhile, but today new stickers are going on the pumps "Contains 10% ethanol"... and at the same moment the 91 premium octane stickers have been replaced with 93 Octane stickers.

Thought I knew a fair amount about octane issues from years of hot rods/timing & tuning and such.

Did the boost to 10% ethanol in itself increase the octane by 2 points? Or did the refinery have to refine the fuel up to 93 to be able to handle or offset the ethanol or something like that? An inquiring and sometimes goofy mind wants to know!
 
Old Nov 13, 2008 | 09:05 AM
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Wow excellent question - I'm interested in this one too...

Here in Calif we dont use ethanol, at least not in my area but i swear the winter fuel blends give about 10%+ LESS mpg's than the summer blends.
 
Old Nov 13, 2008 | 10:06 AM
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I blame algore for all this BS,,,,
 
Old Nov 13, 2008 | 10:20 AM
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Originally Posted by NetMinder
I blame algore for all this BS,,,,
Yep. The Ethanol-Disciples all claim it's better for the atmosphere, but first the difference is so slight that since the gas mileage goes down faster & you have to buy more sooner, it pretty much negates the whole "better for the environment" theory. Not to mention it's driven up the price of corn and has made groceries more expensive...

"I invented the internet..." blah blah blah
 
Old Nov 13, 2008 | 10:28 AM
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Originally Posted by Big Sled
Haven't seen a thread with this particular octane issue, so...

Did the boost to 10% ethanol in itself increase the octane by 2 points? Or did the refinery have to refine the fuel up to 93 to be able to handle or offset the ethanol or something like that? An inquiring and sometimes goofy mind wants to know!
The higher the octane number, the less likely the fuel will detonate before the spark plug fires. Pure ethanol has a very high octane rating, something like 115. So, depending on how much ethanol they blended in, and the native octane rating of the fuel, probably yes, 10% ethanol could increase the octane rating a couple of numbers.

As to fuel economy and horse power. Octane rating is not a power rating. Higher octane fuel only translates into more power if you use it in a high compression engine. More likely than not, a higher octane fuel will have less heat energy than a lower octane fuel.

Disclaimer: opinions based on a 30 year old Gator chemisty degree.
 
Old Nov 13, 2008 | 10:29 AM
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Ethanol is the highest-performance fuel on the market, with an octane rating of 113 in its pure form.
Ethanol-enriched fuel contains more oxygen — so it burns cleaner
Fuel enriched with 10% ethanol burns cleaner, helping to remove gummy deposits in the fuel system so engines can run with optimal performance.
Enriching fuel with 10% ethanol helps it to burn cleaner and at a cooler temperature, which can add to engine longevity.

So I would say the reason for the 2% octane increase is the ethanol.
 
Old Nov 13, 2008 | 10:36 AM
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Ah, knew there were some chemists out there. Thanks ... and it sounds like the local gas got its 2 points of octane boost just inherently from the refinery upping the ethanol content. The regular grade also instantly popped up to 87 from its prior 85.5 due to the ethanol addition.
Thanks!
 
Old Nov 13, 2008 | 11:08 AM
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Yes, ethanol has a higher octane rating than gasoline. You need a much higher compression engine to burn pure ethanol, which is why normal cars can only go up to 10% ethanol. This despite having a lower amount of energy per unit volume than regular gasoline. Higher octane DOES NOT equal higher performance, it is a measure of a fuel's tendency to burn rather than explode.

Most environmental organizations are against ethanol for a variety of reasons. http://hoosier.sierraclub.org/chapter/n0009.html It was put in place by legislators and lobbyists from corn producing states and the lobby very effectively promoted the idea that it was "good for the environment," making opposition to it political suicide. Now that the facts are more widely known I think (hope?) the vote would have gone differently.

And BTW, Al Gore never actually claimed to have invented the internet, he merely claimed to have been an early supporter of technology, including the R&D that eventually led to it (which he was). http://www.snopes.com/quotes/internet.asp

Vint Cerf, the "father of the internet" said "Al Gore had seen what happened with the National Interstate and Defense Highways Act of 1956, which his father introduced as a military bill. It was very powerful. Housing went up, suburban boom happened, everybody became mobile. Al was attuned to the power of networking much more than any of his elective colleagues. His initiatives led directly to the commercialization of the Internet. So he really does deserve credit." http://www.esquire.com/print-this/wh...vint-cerf-0508
 
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Old Nov 13, 2008 | 11:35 AM
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Originally Posted by barjbar
Ethanol is the highest-performance fuel on the market, with an octane rating of 113 in its pure form.
Octane is only relevent in high compression engines. Most, if not all, vehicles will get dramatically worse gas mileage and horsepower from ethanol fuels.

Originally Posted by barjbar
Ethanol-enriched fuel contains more oxygen — so it burns cleaner
Industry hype all over the net. Show me the relevant reactions. The one oxygen atom in ethanl could just as easily produce water.

Originally Posted by barjbar
Fuel enriched with 10% ethanol burns cleaner, helping to remove gummy deposits in the fuel system so engines can run with optimal performance.
And that gum is clogging filters, fuel lines, carbs and injectors.

Originally Posted by barjbar
Enriching fuel with 10% ethanol helps it to burn cleaner and at a cooler temperature, which can add to engine longevity.
Cooler yes, because it's producing less energy. Longer engine life from lower temps? Show me the relevent research. Engines wear out for a variety of reasons.

Sorry to be so aggressive, but your comments are a straight clip and past from the Ethanol industry website. Currently it takes more energy to produce ethanol than is in the final product. And for this we pay the same price and get reduced gas mileage.
 
Old Nov 13, 2008 | 11:35 AM
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From Thunder Press' Kip Woodring tech article....http://www.thunderpress.net/MONTH_AR...headMemo.shtml
 
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