Nitrogen
The idea is that, because nitrogen does not expand and contract as much with temperature changes, nitrogen is better for your tires.
Here is the first thing that comes to mind:
If it does not expand and contract as much and you are supposed to check your tires cold (which you are), then how can you possibly figure out what the correct pressure of nitrogen in your tire should be? With that said, I'm sure there will be plenty on here that will tell us the wonders of nitrogen in their tires.
Nitrogen does not stay in your tire any better than plain old compressed air. Nitrogen does not cause you to have to check your tire pressure less. What nitrogen actually does do for a (aircraft) tire is maintain a more consistent pressure when extreme altitude and temperature changes are a factor. This is why it is used on aircraft tires. Keep in mind that even aircraft tire pressures are checked frequently.
I have been an aircraft mechanic since 1986 and I do base this opinion on fact. If you wanna put nitrogen in your tires then go for it, it will not hurt anything. I'm not sure how you would figure out if you should be running a little more pressure cold than you would with air to compensate for the lack of heat expansion. You still need to check your pressure at least every 2 weeks.
If you think I'm wrong about this, tell me why and prove it.

Ron
most of the times I've seen or heard someone talking about this, it's been in reference to offroading trucks, never really seen folks hyping this for passenger cars - unless you're going to be taking it offroad

and even then I'd think it would be better only for keeping your tires at a consistent pressure during the trek, but there's no way I could justify, in my own head, paying more to put it in my tires. the compressor I have at home has a filter set on it for the air tools I have, so there's minimal moisture getting into the air of my tires anyway.
Cheers.
www.getnitrogen.org/pdf/graham.pdf
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